IEEE Photonics Seminar Dr. Tim Lian Date: October 14 Time: Noon Location: Dell Butcher Hall 180 Efficient Light-driven Long Distance Charge Separation and H2 Generation in Semiconductor Quantum Rod Heterostructures Quantum confined semiconductor nanocrystals (0D quantum dots, 1D quantum rods and 2D quantum platelets) have been intensively investigated as light harvesting and charge separation materials for photovoltaic and photocatalytic applications. The efficiency of these semiconductor nanocrystal-based devices depends on many fundamental processes, including light harvesting, carrier relaxation, exciton localization and transport, charge separation and charge recombination. The competition between these processes determines the overall solar energy conversion (solar to electricity or fuel) efficiency. Quantum confined semiconductor nano-heterostructures, combining two or more material components, offer unique opportunities to control their charge separation properties by tailoring their compositions, dimensions and spatial arrangement. Further integration of catalysts (heterogeneous or homogeneous) to these materials form multifunctional nano-heterostructures. Using 0D, 1D and 2D CdSe/CdS/Pt heterostructures as model systems, we directly probe the above-mentioned fundamental exciton and carrier processes by transient absorption and time-resolved fluorescence spectroscopy. We are examining how to control these fundamental processes through the design of heterostructures to achieve long-lived charge separation and efficient H2generation. In this talk, we will discuss a new model for exciton dissociation by charge transfer in quantum dots (i.e. Auger assisted electron transfer), mechanism of 1D exciton transport and dissociation in nanorods, and key factors limiting H2 generation efficiency in CdSe/CdS/Pt nanorod heterostructures. (ref. Nano let. (2014) 14 , 1263-1269; JACS (2014), 136, 7708-7716; Accounts of chemical research (2015) 48, 851-859; Ann. Rev. Phys. Chem., (2016), 67, 259; Chem. Soc. Rev. (2016), 45, 3781) Bio: Tianquan (Tim) Lian received PhD degree from University of Pennsylvania (under the supervision of late Prof. Robin Hochstrasser) in 1993. After postdoctoral training with Prof. Charles B. Harris in the University of California at Berkeley, Tim Lian joined the faculty of chemistry department at Emory University in 1996. He was promoted to Associate Professor in 2002, Full Professor in 2005, Winship Distinguished Research Professor in 2007, and William Henry Emerson Professor of Chemistry in 2008. Tim Lian is the Co-Editor-In-Chief of Chemical Physics (since 2012), a Kavli fellow (since 2012), APS fellow (since 2015) and recipient of the NSF CAREER award and Alfred P. Sloan fellowship. Tim Lian research interest is focused on ultrafast energy and charge transfer dynamics in photovoltaic and photocatalytic nanomaterials and at their interfaces. Location: Room: 180 Bldg: Dell Butcher 180 Rice University, 6100 Main Street Houston, Texas 77005